Barton reaction is a photochemical conversion of nitrite ester into δ-nitroso alcohol upon exposure to ultraviolet radiation. The reaction involves homolytic cleavage of RO–NO followed by δ-hydrogen abstraction, and takes place in a liquid phase. This reaction is popularly called as Barton nitrite ester reaction. The geometry of the 6-membered radical intermediate accounts for the selectivity of the δ-hydrogen.
UV Radiation
Nitrite Ester To Nitroso Alcohol
Application
Corticosterone To Aldosterone
Nobel Prize, 1969
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